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See Also:

SiO2, Si3N4 Properties

Semicon Manufacturing

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Wafer Fab:  Glassivation      

      

Glassivation is the deposition of the final passivating layer on top of the die to protect the die from mechanical damage and corrosion.   As the name implies, this final layer is often composed of an amorphous insulating material, or glass.

    

Silicon nitride (Si3N4) is a common glassivating material because of its suitability for this purpose.  Highly resistant to diffusion, it is almost impenetrable to moisture and ionic contaminants such as sodium (Na).  It can also be deposited with a low residual compressive stress, making it less prone to delamination or cracking.  Its interfacing with the underlying metal layers is also very conformal.  Finally, it can be prepared with very low pinhole density.  Since silicon nitride has a high dielectric constant, it is not popular as an interlayer dielectric for the simple reason that it results in a high inter-metal capacitance.

    

Silicon nitride can be deposited using plasma-enhanced chemical vapor deposition (PECVD) or low-pressure chemical vapor deposition (LPCVD), although the former is the technique of choice for glassivation purposes because it allows a lower processing temperature.

       

See also:  Dielectric

  

                  

Figure 1.  Example of an LPCVD system that can

be used to deposit silicon nitride on substrates

     

                                        

BOOKS on GLASSIVATION for SALE at Amazon.com:

          

1)  Silicon Nitride for Microelectronic Applications, Part 1 (Handbook of electronic materials, v. 3, 6)

2)  Silicon Nitride and Silicon Dioxide Thin Insulating Films: Proceedings of the Symposium on Silicon Nitride and Silicon Dioxide Thin Insulating Films (Proceedings; V. 97-9)

3)  Silicon Nitride in Electronics (Materials Science Monographs 34)

    

    

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